Affiliation:
1. Key Laboratory of Optical Field Manipulation of Zhejiang Province, Department of Physics, Zhejiang Sci-Tech University 1 , Hangzhou 310018, People's Republic of China
2. Hangzhou Zhongneng Photoelectricity Technology Co., Ltd 2 ., Hangzhou 310018, People's Republic of China
Abstract
A self-cleaning transparent pn junction in perovskite SrTiO3 QDs modified CuGaO2/Zn2SnO4 nanoarrays is prepared via the hydrothermal-solgel-surface plasma (SP) method. The CuGaO2/SrTiO3 QDs/Zn2SnO4 exhibits transmittance of ∼85%–90%, photovoltaic enhancement of ∼1.8 × 103-folds (photovoltaic conversion efficiency of ∼1.25%), stable output in 5 months, and good hydrophobicity (contact angle of ∼138.1°). The main reasons are mainly attributed to the SrTiO3 QDs and SP modification; besides the appropriate Fermi level and high quantum yield can improve the carrier kinetic equilibrium for balancing transparency-photovoltaic conversion efficiency, the SP modification can enhance the solar and carrier efficiency further, meanwhile achieving self-cleaning. Additionally, the CuGaO2 orderly nanoarrays can release stress, increase solar efficiency, and promote carrier transportation, in order to balance the structural stability, transparency, and photovoltaic efficiency.
Funder
National Natural Science Foundation of China
Natural Science Foundation of Zhejiang Province