Highly active nickel-loaded β-SiC nanowire catalysts for photocatalytic H2 production by water splitting

Author:

Wang Ying12ORCID,Yang Shuai1ORCID,Li Xiang1,Huang Wei1,He Zheng-fa1,Fu Xian-liang12ORCID,Zhu Li12,Xu Man12

Affiliation:

1. Chaozhou Branch of Chemistry and Chemical Engineering Guangdong Laboratory 1 , Chaozhou 521000, China

2. Engineering Research Center of Environmental Materials and Membrane Technology of Hubei Province, School of Materials Science and Engineering, Wuhan Institute of Technology 2 , Wuhan 430073, China

Abstract

Developing a highly efficient water-splitting photocatalyst for hydrogen production under visible light is urgent. In this study, β-SiC nanowire photocatalysts loaded with 0.01–0.1 wt. % nickel were prepared. Their microstructure and hydrogen production activity were studied. The catalyst with 0.05 wt. % nickel and a sacrificial agent Na2S–Na2SO3 shows the highest hydrogen production rate of 375.4 µmol g−1 h−1 since the loaded nickel prohibits the recombination of photogenerated electron–hole pairs in the system, which enhances the photocatalytic activity.

Funder

Guangdong Major Project of Basic and Applied Basic Research

Self-Innovation Research Funding Project of Hanjiang Laboratory

Key Research and Development Project of Hubei Province

Publisher

AIP Publishing

Subject

General Physics and Astronomy

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