Hierarchical approximations to the nucleation work in the entire range of metastability

Abstract

The work W to form a nucleus (also known as the critical nucleus) is a key quantity in the description of nucleation phenomena because of its exponentially strong effect on the nucleation rate. The present study provides a general approximate expression for W, which comprises a hierarchy of approximations to the dependence of W on the experimentally controlled overpressure Δp of a nucleating multicomponent phase. This general expression is used to derive explicit formulas for the lowest-order members of the W(Δp) hierarchy as well as for the respective lowest-order approximations to the Δp dependences of the nucleus surface tension, the nucleus radius, the Gibbs–Tolman length, and the stationary nucleation rate. The second-order and the third-order approximations to the W(Δp) dependence are confronted with available W(Δp) data, and the latter is found to agree very well with the data. The results obtained are applicable to homogeneous single-component or multicomponent nucleation from the binodal to the spinodal of the old phase, i.e., in the entire range of the old-phase metastability.