380-keV Ar+-irradiation effects on optical phonons in graphite studied with transient reflection measurement

Author:

Kimata Tetsuya12ORCID,Kato Taichi13,Takagi Itsuki13ORCID,Konno Yuma13ORCID,Okazaki Hiroyuki2ORCID,Yamamoto Shunya2ORCID,Yamaki Tetsuya2ORCID,Nakamura Kazutaka G.13ORCID

Affiliation:

1. Laboratory for Materials and Structures, Institute of Innovative Research, Tokyo Institute of Technology 1 , 4259 Nagatsuta, Yokohama 226-8503, Japan

2. Takasaki Institute for Advanced Quantum Science, National Institutes for Quantum Science and Technology 2 , 1233 Watanuki, Takasaki, Gunma 370-1292, Japan

3. Department of Materials Science and Engineering, Tokyo Institute of Technology 3 , 4259 Nagatsuta, Yokohama 226-8503, Japan

Abstract

In this work, we performed transient reflection measurements using the pump–probe protocol to investigate the influence of lattice defects induced by 380 keV argon (Ar) ions on the phonon dynamics of interlayer shearing (E2g1) and in-plane carbon stretching (E2g2) modes in highly oriented pyrolytic graphite (HOPG). The frequency and decay rate of E2g1- and E2g2-mode phonons were changed significantly at the fluence of 1×1014 ions/cm2. This indicated that significant structural changes in HOPG due to 380 keV Ar-ion irradiation were expressed as changes in the frequency and decay rate of phonons. In HOPG irradiated with 380 keV Ar+ at the fluence of 1×1014 ions/cm2, our measurement results indicated that compressive and tensile stresses contributed to in-plane and interlayer graphite structures, respectively.

Funder

Japan Society for the Promotion of Science

Publisher

AIP Publishing

Subject

General Physics and Astronomy

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