Thermal transport and topological analyses of the heat-carrying modes and their relevant local structures in variously dense amorphous alumina

Abstract

Engineering the thermal conductivities of amorphous materials is important for thermal management of various semiconducting devices. However, controlling the heat carriers—long-range propagating propagons and short-range hopping diffusons—in disordered lattices is difficult because the carriers are strongly correlated with lattice disorder. To clarify the relationship between lattice disorder and heat conduction, we must simultaneously investigate the important local structures hidden in a disordered system and the microscopic transport characteristics of propagons and diffusons. Here, we explore the variations in spectral thermal conductivity and the relevant local structures in amorphous alumina (a-Al2O3) at different densities by performing the spectral thermal transport and persistent homology analyses. As the density increases, the thermal conductivity of the high-frequency diffusons linearly increases but those of the propagons and low-frequency diffusons remain constant. The density increase enhances the local strain, thereby increasing the mean free paths of the high-frequency diffusons. The density of states competes with diffusivity, lowering the sensitivity of the density response to the thermal conductivity of low-frequency heat carriers. Furthermore, from the obtained topological features of the connections between the oxygen atoms, we inferred that the collapsed network of six-coordinated AlO6 octahedron clusters underlies the transport of high-frequency diffusons. Besides revealing the conductive pathways of heat-carrying modes in disordered lattices, topology-assisted spectral thermal transport analysis is useful for tailoring the thermal conductivities of amorphous materials.