Affiliation:
1. Applied Chemicals and Materials Division, National Institute of Standards and Technology, Boulder, Colorado 80305, USA
Abstract
In this work, new thermodynamic models for refrigerant mixtures are provided for the binary pairs R-1234yf/134a, R-1234yf/1234ze(E), and R-134a/1234ze(E) based on new reference measurements of speed of sound, density, and bubble-point pressures. Fitting the very accurate liquid-phase speed of sound and density data reproduces the bubble-point pressures to within close to their uncertainty, yielding deviations in density less than 0.1% and speed of sound deviations less than 1% (and less than 0.1% for R-1234yf/134a). Models are also presented for the binary pairs R-125/1234yf, R-1234ze(E)/227ea, and R-1234yf/152a based solely on bubble-point measurements.
Funder
Strategic Environmental Research and Development Program
Subject
Physical and Theoretical Chemistry,General Physics and Astronomy,General Chemistry
Cited by
10 articles.
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1. Isothermal (vapor + liquid) equilibrium measurements and correlation of the binary mixture 3,3,3-trifluoropropene (R1243zf) + isobutane (R600a) at temperatures from 283.15 to 323.15 K;International Journal of Refrigeration;2024-05
2. Gaseous speed of sound and virial coefficients for 2,3,3,3-tetrafluoropropene (R1234yf) + 1,1,1,2-tetrafluoroethane (R134a) binary mixture;International Journal of Refrigeration;2023-10
3. A General Model for Thermodynamic Properties of Fluid Mixtures Based on Helmholtz Energy Formulations for the Components. Virial Expansion and Reduction to van der Waals Mixing Rules;International Journal of Thermophysics;2023-07-31
4. Vapor and Liquid (p–ρ–T–x) Measurements of Binary Refrigerant Blends Containing R-32, R-152a, R-227ea, R-1234yf, and R-1234ze(E);Journal of Chemical & Engineering Data;2023-06-14
5. Vapor and Liquid (p–ρ–T–x) Measurements of Binary Refrigerant Blends Containing R-134a, R-1234yf, and R-1234ze(E);Journal of Chemical & Engineering Data;2023-06-14