Optimization of the efficiency of a nanowire solar cell by nanowire tapering

Abstract

Thermodynamics shows that the open-circuit voltage (Voc) of a solar cell is dependent on the external radiative efficiency at Voc. In planar solar cells with low photon recycling probability, this efficiency is limited to 2% due to total internal reflection of the emitted light, providing a penalty of 101 mV to the Voc. Tapered nanowire solar cells allow for an adiabatic expansion of the guided optical mode into air, allowing to reduce this loss. For this purpose, we first perform simulations of the photon escape probability in tapered nanowires with both finite difference time domain simulations as well as with rigorous coupled-wave analysis, showing photon escape probabilities up to 47.2% for normally tapered nanowires and up to 92% for inversely tapered nanowires. We subsequently show that by fine tuning the recipe for reactive ion etching of the tapered InP nanowires, we can decrease the nanowire tapering angle from 4.5° down to 1.8°, allowing to significantly increase the measured external radiative efficiency. We finally observe an open-circuit voltage of 0.746 V at a tapering angle of 2.46°.