Affiliation:
1. Centre for Research in Computational Thermochemistry (CRCT), Department of Chemical Engineering, Polytechnique Montréal , Box 6079, Station Downtown, Montréal, Quebec H3C 3A7, Canada
Abstract
This study outlines an extensive investigation of crystallographic data and thermodynamic properties (including solid-solid transition and fusion) for sodium dichromate, potassium dichromate, sodium dimolybdate, potassium dimolybdate, sodium ditungstate, and potassium ditungstate. A thorough literature review was conducted to obtain a good understanding of the data available in the literature, and a critical and complete evaluation has been performed from room temperature to above the melting temperatures. This work is one of the key steps towards the development of a thermodynamic model for the Na+, K+//Cl−, SO42−, CO32−, CrO42−, Cr2O72−, MoO42−, Mo2O72−, WO42−, W2O72−, O2− system, relevant for high temperature corrosion in atmospheres containing O–H–S–C–Cl and alkali salts.
Funder
Canada Research Chair in Computational Thermodynamics for High Temperature Sustainable Processes
Subject
Physical and Theoretical Chemistry,General Physics and Astronomy,General Chemistry
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