Tuning nonequilibrium phase transitions with inertia

Author:

Omar Ahmad K.12ORCID,Klymko Katherine34ORCID,GrandPre Trevor5ORCID,Geissler Phillip L.67ORCID,Brady John F.8ORCID

Affiliation:

1. Department of Materials Science and Engineering, University of California 1 , Berkeley, California 94720, USA

2. Materials Sciences Division, Lawrence Berkeley National Laboratory 2 , Berkeley, California 94720, USA

3. NERSC, Lawrence Berkeley National Laboratory 3 , Berkeley, California 94720, USA

4. Computational Research Division, Lawrence Berkeley National Laboratory 4 , Berkeley, California 94720, USA

5. Department of Physics, University of California 5 , Berkeley, California 94720, USA

6. Department of Chemistry, University of California 6 , Berkeley, California 94720, USA

7. Chemical Sciences Division, Lawrence Berkeley National Laboratory 7 , Berkeley, California 94720, USA

8. Division of Chemistry and Chemical Engineering, California Institute of Technology 8 , Pasadena, California 91125, USA

Abstract

In striking contrast to equilibrium systems, inertia can profoundly alter the structure of active systems. Here, we demonstrate that driven systems can exhibit effective equilibrium-like states with increasing particle inertia, despite rigorously violating the fluctuation–dissipation theorem. Increasing inertia progressively eliminates motility-induced phase separation and restores equilibrium crystallization for active Brownian spheres. This effect appears to be general for a wide class of active systems, including those driven by deterministic time-dependent external fields, whose nonequilibrium patterns ultimately disappear with increasing inertia. The path to this effective equilibrium limit can be complex, with finite inertia sometimes acting to accentuate nonequilibrium transitions. The restoration of near equilibrium statistics can be understood through the conversion of active momentum sources to passive-like stresses. Unlike truly equilibrium systems, the effective temperature is now density dependent, the only remnant of the nonequilibrium dynamics. This density-dependent temperature can in principle introduce departures from equilibrium expectations, particularly in response to strong gradients. Our results provide additional insight into the effective temperature ansatz while revealing a mechanism to tune nonequilibrium phase transitions.

Funder

National Science Foundation

U.S. Department of Energy

Publisher

AIP Publishing

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

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