Apparent ferrimagnetism in Sr(Fe0.2Mn0.2Co0.2Ti0.2V0.2)O3 high-entropy oxide perovskite thin films

Author:

Regmi Balaram1ORCID,Miertschin Duncan1ORCID,Cocconcelli Maria2ORCID,Stramaglia Federico3ORCID,Crater Davis1ORCID,Yao Lide4ORCID,Piamonteze Cinthia3ORCID,van Dijken Sebastiaan5ORCID,Farhan Alan1ORCID

Affiliation:

1. Department of Physics, Baylor University 1 , Waco, Texas 76798, USA

2. Dipartimento di Fisica, Politecnico di Milano 2 , 20133 Milano, Italy

3. Paul Scherrer Institute 3 , Forschungsstrasse 111, 5232 Villigen PSI, Switzerland

4. OtaNano-Nanomicroscopy Center, Aalto University School of Science 4 , P.O. Box 15100, FI-00076 Aalto, Finland

5. Department of Applied Physics, Aalto University School of Science 5 , P.O. Box 15100, FI-00076 Aalto, Finland

Abstract

We present a study on the structural and magnetic properties of Sr(Fe0.2Mn0.2Co0.2Ti0.2V0.2)O3 (S5BO) high-entropy oxide perovskite thin films. We use synchrotron-based x-ray absorption spectroscopy employing x-ray magnetic circular dichroism (XMCD) and reveal an enhanced presence of high-spin Co2+, which appears to feature a magnetic response opposing that of the two other magnetic transition metal elements, Fe and Mn. This is marked by both opposite XMCD signals and an inverted XMCD hysteresis loop for Co, while Fe and Mn show regularly shaped hysteresis curves, as the picture of a ferrimagnetic ground state emerges for S5BO.

Funder

Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung

Publisher

AIP Publishing

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