Enhanced room-temperature magnetic field effect on spin-polarized excitons of cesium lead bromine-magnetite nanocomposites

Abstract

The generation and manipulation of spin-polarized electrons are the basis of spintronic applications. Spin injection from a ferromagnetic surface or heterojunction to a semiconductor adjacent layer is often used to create spin-polarized carriers; however, for halide perovskites, due to the mismatch of lattice parameters with most ferromagnets at room temperature, this spin injection is challenging. In this study, we synthesize all-inorganic perovskite CsPbBr3 surrounded by Fe3O4 magnetic nanoparticles. It is found that this nanocomposite shows both magnetization and magnetic field-induced circularly polarized photoluminescence at room temperature. Specifically, with the attachment of Fe3O4 nanoparticles closely on the surface of CsPbBr3 nanocrystals, both the degree of circular polarization and g-factor enhanced by 3.5 times compared with that of pure CsPbBr3. The phenomenon should be due to the formation of exciton magnetic polaron through the coupling of the magnetic aligned nanoparticles with the excitonic state of the host semiconductor in the external magnetic field. The effective spin injection provides a method of controlling the excitonic spin polarization of all-inorganic halide perovskites for spintronic applications.