Enhancement of electromechanical response in curved antiferroelectric AgNbO3 ceramics by flexoelectric effect

Abstract

AgNbO3 is a typical antiferroelectric ceramic with weak ferroelectricity at room temperature. Due to this feature, AgNbO3 has received a lot of attention in electromechanical applications, but most of these studies have focused on the doping of other elements in AgNbO3. In this study, curved AgNbO3 ceramics were fabricated using a gravity-driven annealing process, and the field-induced strains were investigated. The curved ceramic exhibited a significantly higher field-induced nominal strain compared to a flat ceramic. Experimental results revealed that the curved AgNbO3 sample exhibited a maximum nominal strain of 1.22%, significantly surpassing the theoretical value of 0.13%. Analysis of various characterizations confirmed the presence of flexoelectricity, and flexoelectricity played an important role in the ultrahigh electromechanical response of curved AgNbO3 ceramics. Additionally, we demonstrated that curved AgNbO3 ceramics can enhance the flexoelectric coefficient. These findings suggest that curved antiferroelectric ceramics can enhance their displacement output, meeting the requirements for applications in large-strain actuators.