Hydrogen migration in triply charged acetylene

Abstract

We report on the direct experimental evidence of hydrogen migration in triply charged acetylene. The roaming hydrogen atom in a triply charged molecular ion is counter intuitive. The three body breakup channel [Formula: see text] is studied using the technique of recoil ion momentum spectroscopy. The triply charged ion was generated in collisions of the neutral parent with a slow highly charged Xe9+ ion. Three different dissociation pathways have been identified and separated, namely, concerted breakup in an acetylene configuration, concerted breakup in a vinylidene configuration, and sequential breakup via a [Formula: see text] intermediate, and the branching ratio for all three pathways are determined.