Emergence of chirality from electron spins, physical fields, and material-field composites

Author:

Kusunose Hiroaki12ORCID,Kishine Jun-ichiro23ORCID,Yamamoto Hiroshi M.24ORCID

Affiliation:

1. Department of Physics, Meiji University 1 , Kawasaki, Kanagawa 214-8571, Japan

2. Quantum Research Center for Chirality, Institute for Molecular Science 2 , Myodaiji, Okazaki 444-8585, Japan

3. Division of Natural and Environmental Sciences, The Open University of Japan 3 , Chiba, Chiba 261-8586, Japan

4. Research Centre of Integrated Molecular Systems, Institute for Molecular Science 4 , Myodaiji, Okazaki 444-8585, Japan

Abstract

In this work, chirality in spin-active electronic states is explained clearly to address confusion about chiral effects recently discovered in materials science. We stress that the electronic toroidal monopole G0 can serve as a measure of chirality. By using the symmetry classification in terms of four distinct types of multipole bases, we extend the concept of chirality from materials to physical fields and material-field composites. Additionally, we illustrate specific examples from physics and chemistry that demonstrate the process of acquiring chirality through the combination of seemingly achiral degrees of freedom, which we term the emergence of chirality. Interference between multiple chiralities exhibiting phenomena specific to handedness is also discussed.

Funder

Japan Society for the Promotion of Science

Institute for Molecular Science

National Institutes of Natural Sciences

Publisher

AIP Publishing

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