A combined melt-stretching and quenching setup for experimental studies of polymer crystallization under complex flow-temperature environments

Abstract

A combined melt-stretching and quenching setup is designed and developed to allow experimental investigations of polymer crystallization under the complex flow-temperature environments comparable to those encountered in the actual industrial processing. The melt-stretching proceeds by two drums rotating in the opposite directions with simultaneous recording of a stress–strain curve, where the Hencky strain and strain rate (≤233 s−1) are adjustable over a large range. After stretching, liquid N2 is used as a cooling medium to quench the free-standing melt, which is sprayed directly to the deformed melt driven by an electric pump. To ensure a high cooling efficiency, a three-way solenoid valve is employed to execute a sequential control of the liquid N2 flow direction to reduce the boil-off of liquid N2 before entering the sample chamber. The melt cooling rate depends on the liquid N2 flow rate controlled by a flow valve, which is up to 221 °C/s when quenching the isotactic polypropylene (iPP) melt with a thickness of 0.28 mm at 150 °C. Two independent temperature control modules are designed to meet the requirements of different stages of melt-stretching and quenching. To verify the capability of the setup, we have performed the melt-stretching and quenching experiments on iPP samples. The setup is demonstrated to be a valuable new tool to study polymer crystallization under coupled flow-cooling fields.