Quasi-nature catalysis. Rhodium-catalyzed C­C bond formation in air and water

Author:

Huang Taisheng1,Venkatraman Sripathy1,Meng Yue1,Nguyen Tien V.1,Kort Daniel1,Wang Dong2,Ding Rui2,Li Chao-Jun1

Affiliation:

1. 1Department of Chemistry, Tulane University, New Orleans, LA 70118, USA

2. 2Center for Molecular Science, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080, P. R. China

Abstract

Transition-metal catalysis is out-grown from dry-boxes where the use of inert gas atmosphere and the exclusion of moisture have been essential. Such a restriction undoubtedly imposes limitations in the application of these reactions in organic synthesis and in the recycling of the catalysts. This article discusses some recent advances of rhodium-catalyzed carbon­carbon bond formations under the natural conditions of air and water.

Publisher

Walter de Gruyter GmbH

Subject

General Chemical Engineering,General Chemistry

Reference3 articles.

1. a;Oi;Chem Lett Chem Commun,1998

2. on green chemistry see In Designing Chemistry for the Environment No ) Chemical By Design : Alternative Synthetic Pathways for Pollution Prevention No Chemical;Anastas;Green Chemistry ACS Symposium Series American Society Benign Symposium Series American Society Science Chem Eng News,1996

3. Rhodium - catalyzed carbonyl addition and conjugated addition with boronic acids in water were also reported recently see;Hayashi;Am Chem Soc Org Chem,2000

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