Vital role of entropy in photochirogenesis-Reference-Cited by-同舟云学术

Vital role of entropy in photochirogenesis

Published:2001-01-01 Issue:3 Volume:73 Page:475-480
ISSN:1365-3075
Container-title:Pure and Applied Chemistry
language:
Short-container-title:

Author:

Inoue Yoshihisa¹,Sugahara Norimitsu,Wada Takehiko

Affiliation:

1. 1Inoue Photochirogenesis Project, ERATO, JST, 4-6-3 Kamishinden, Toyonaka 565-0085, Japan

Abstract

The effects of temperature, pressure, solvent, and substrate concentration upon several enantio- and diastereodifferentiating photochemical reactions have been investigated and discussed in detail. These entropy-related external factors, which manipulate the weak electronic and steric interactions in the excited state, dynamically control the stereochemical outcome of asymmetric photochemical reactions, and even switch the product chirality. A global view on the "entropy chemistry" and its potential applications are also discussed.

Publisher

Walter de Gruyter GmbH

Subject

General Chemical Engineering,General Chemistry

Link

https://www.degruyter.com/document/doi/10.1351/pac200173030475/pdf

Reference3 articles.

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2. Pressure effects on thermal and some photochemical reactions have been reviewed in detail a le Pressure effects on achiral photochemical reactions were also reported;Asano;Noble Chem Rev Chem Rev Am Chem Soc Org Chem Chem Ber,1978

3. We also thank Dr Hembury for assistance in the preparation of this manuscript and Vital role of entropy in photochirogenesis REFERENCES;Guy;Pure Applied Chemistry Chem Rev,2001

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