Spiroketals: Toward the synthesis of 39-oxobistramide K-Reference-Cited by-同舟云学术

Spiroketals: Toward the synthesis of 39-oxobistramide K

Published:2012-02-29 Issue:7 Volume:84 Page:1567-1574
ISSN:1365-3075
Container-title:Pure and Applied Chemistry
language:
Short-container-title:

Author:

Commandeur Malgorzata¹,Commandeur Claude¹,Cossy Janine¹

Affiliation:

1. 1Laboratoire de Chimie Organique Associé au CNRS, ESPCI ParisTech, 10 rue Vauquelin, 75231 Paris Cedex 05, France

Abstract

An advanced spiroketal intermediate toward the synthesis of 39-oxobistramide K was prepared, fragment C14–C40. This fragment was obtained in 19 steps with an overall yield of 6.2 % using a FeCl3-catalyzed spiroketalization as the key step.

Publisher

Walter de Gruyter GmbH

Subject

General Chemical Engineering,General Chemistry

Link

https://www.degruyter.com/downloadpdf/journals/pac/84/7/article-p1567.xml

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