In search of 3d/4f-metal single-molecule magnets: Nickel(II)/lanthanide(III) coordination clusters-Reference-Cited by-同舟云学术

In search of 3d/4f-metal single-molecule magnets: Nickel(II)/lanthanide(III) coordination clusters

Published:2013-01-21 Issue:2 Volume:85 Page:315-327
ISSN:1365-3075
Container-title:Pure and Applied Chemistry
language:
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Author:

Polyzou Christina D.¹,Efthymiou Constantinos G.²,Escuer Albert³,Cunha-Silva Luís⁴,Papatriantafyllopoulou Constantina²,Perlepes Spyros P.¹

Affiliation:

1. 1Department of Chemistry, University of Patras, 265 04 Patras, Greece

2. 2Department of Chemistry, University of Cyprus, 1678 Nicosia, Cyprus

3. 3Departament de Quimica Inorgànica and Institut de Nanociéncia i Nanotecnologia, Universitat de Barcelona (IN2 UB), Av. Diagonal 645, 08028 Barcelona, Spain

4. 4REQUIMTE and Department of Chemistry and Biochemistry, Faculty of Sciences, University of Porto, 4169-007 Porto, Portugal

Abstract

The importance of 3d/4f-metal cluster chemistry is outlined, and the employment of 2-pyridyl ketone- and 2-pyridyl oxime-based ligands for the preparation of low-nuclearity NiII/LnIII complexes (Ln = lanthanide) is reviewed. The synthetic utility of the “metal complexes as ligands” and “one-pot” approaches is critically discussed. The small nuclearity of the products permits the in-depth analysis of their magnetic properties.

Publisher

Walter de Gruyter GmbH

Subject

General Chemical Engineering,General Chemistry

Link

https://www.degruyter.com/downloadpdf/journals/pac/85/2/article-p315.xml

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