Rhodium-catalyzed CO gas-free carbonylative cyclization using aldehydes-Reference-Cited by-同舟云学术

Rhodium-catalyzed CO gas-free carbonylative cyclization using aldehydes

Published:2008-01-01 Issue:5 Volume:80 Page:1079-1087
ISSN:1365-3075
Container-title:Pure and Applied Chemistry
language:
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Author:

Morimoto Tsumoru¹,Fujioka Masahiko¹,Fuji Koji¹,Tsutsumi Ken¹,Kakiuchi Kiyomi¹

Affiliation:

1. 1Graduate School of Materials Science, Nara Institute of Science and Technology (NAIST), Takayama, Ikoma, Nara 630-0192, Japan

Abstract

A new protocol for CO gas-free carbonylation, in which aldehydes are used as a substitute for CO, is described. The protocol consists of two Rh-mediated processes; the Rh-mediated decarbonylation of aldehydes, which leads to the formation of Rh carbonyl, and subsequent Rh-catalyzed carbonylative cyclization utilizing the in situ formed Rh carbonyl species.

Publisher

Walter de Gruyter GmbH

Subject

General Chemical Engineering,General Chemistry

Link

https://www.degruyter.com/document/doi/10.1351/pac200880051079/pdf

Reference35 articles.

1. Plenum New;Colquhoun,1991

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