Rhodium- and iridium-catalyzed oxidative coupling of benzoic acids with alkynes and alkenes-Reference-Cited by-同舟云学术

Rhodium- and iridium-catalyzed oxidative coupling of benzoic acids with alkynes and alkenes

Published:2008-01-01 Issue:5 Volume:80 Page:1127-1134
ISSN:1365-3075
Container-title:Pure and Applied Chemistry
language:
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Author:

Satoh Tetsuya¹,Ueura Kenji¹,Miura Masahiro¹

Affiliation:

1. 1Department of Applied Chemistry, Faculty of Engineering, Osaka University, Suita, Osaka 565-0871, Japan

Abstract

The oxidative coupling of benzoic acids with alkynes and alkenes effectively proceeds in the presence of a Rh catalyst and an appropriate oxidant to produce the corresponding isocoumarin and phthalide derivatives, respectively. Interestingly, by using an Ir catalyst in place of Rh, the acids and alkynes undergo 1:2 coupling accompanied by decarboxylation to afford naphthalene derivatives exclusively.

Publisher

Walter de Gruyter GmbH

Subject

General Chemical Engineering,General Chemistry

Link

https://www.degruyter.com/document/doi/10.1351/pac200880051127/pdf

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