Affiliation:
1. 1Department of Chemistry and Biochemistry, University of Colorado, Boulder, CO 80309-0215, USA
Abstract
After a brief introduction to the electronic structure of the three-dimensionally aromatic icosahedral closo-monocarbadodecaborate anion CB11H12-, some recent results for its permethylated version, CB11Me12- and three highly reactive electroneutral analogs are presented and discussed. These are the radical CB11Me12·, the boronium ylide CB11Me11 with a naked boron vertex, and the isomeric carbonium ylide with a naked carbon vertex. These ylides are probably better viewed as unusual types of singlet borylene and carbene, respectively.
Subject
General Chemical Engineering,General Chemistry
Reference30 articles.
1. Schreiber Ph dissertation University of Boulder CO;Colorado,2007
Cited by
20 articles.
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