Affiliation:
1. 1State Key Laboratory and Institute of Elemento-organic Chemistry, Nankai University, Tianjin 300071, China
Abstract
Chiral spiro phosphorus ligands including monophosphoramidites and diphosphines, which contained 1,1'-spirobiindane as a backbone, were designed and synthesized. These spiro ligands were proven to be highly efficient for rhodium- and ruthenium-catalyzed asymmetric hydrogenations of prochiral olefins and ketones with excellent enantioselectivities.
Subject
General Chemical Engineering,General Chemistry
Cited by
18 articles.
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