Recent developments in the chemistry of low-coordinated organophosphorus compounds

Author:

Yoshifuji Masaaki1

Affiliation:

1. 1Department of Chemistry, Graduate School of Science, Tohoku University, Sendai 980-8578, Japan

Abstract

Sterically protected organophosphorus compounds are described, involving diphosphenes, phosphaethenes, diphosphinidenecyclobutenes (DPCBs), phosphaalkynes, phosphaquinones, diphosphathienoquinones, and so on of coordination number 2 or 1. Application of the DPCBs as well as phosphinophosphaethenes as a ligand of transition-metal catalysts for several organic coupling reactions has been investigated.

Publisher

Walter de Gruyter GmbH

Subject

General Chemical Engineering,General Chemistry

Reference7 articles.

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3. a a;Toyota;Chem Lett Organomet Chem Bull Chem Soc Jpn Chem Soc Dalton Trans Pure Appl Chem Org Chem Jpn,1991

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5. a Idemitsu Petrochemical Co Patent WO September;Ikeda;Angew Chem Ed and Ltd,2000

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