Combined coinage metal catalysis for the synthesis of bioactive molecules-Reference-Cited by-同舟云学术

Combined coinage metal catalysis for the synthesis of bioactive molecules

Published:2010-05-02 Issue:7 Volume:82 Page:1529-1536
ISSN:1365-3075
Container-title:Pure and Applied Chemistry
language:
Short-container-title:

Author:

Krause Norbert¹,Aksin-Artok Özge¹,Breker Viola¹,Deutsch Carl¹,Gockel Birgit¹,Poonoth Manojkumar¹,Sawama Yoshinari¹,Sawama Yuka¹,Sun Tao¹,Winter Christian¹

Affiliation:

1. 1Department of Organic Chemistry, Dortmund University of Technology, Otto-Hahn-Strasse 6, D-44227 Dortmund, Germany

Abstract

The use of the coinage metals copper, silver, and gold enables an efficient and stereo-selective assembly of bioactive heterocycles via allenic intermediates. The synthesis of functionalized allenes by SN2'-substitution or SN2'-reduction is mediated or catalyzed by copper, whereas silver and gold are the catalysts of choice for subsequent 5- or 6-endo-cyclizations. Overall, this sequence proceeds with efficient center-to-axis-to-center chirality transfer.

Publisher

Walter de Gruyter GmbH

Subject

General Chemical Engineering,General Chemistry

Link

https://www.degruyter.com/downloadpdf/journals/pac/82/7/article-p1529.xml

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