Concerning the ring-opening polymerization of lactide and cyclic esters by coordination metal catalysts-Reference-Cited by-同舟云学术

Concerning the ring-opening polymerization of lactide and cyclic esters by coordination metal catalysts

Published:2010-06-19 Issue:8 Volume:82 Page:1647-1662
ISSN:1365-3075
Container-title:Pure and Applied Chemistry
language:
Short-container-title:

Author:

Chisholm Malcolm H.¹

Affiliation:

1. 1Department of Chemistry, The Ohio State University, 100 W. 18th Ave., Columbus, OH 43210, USA

Abstract

A summary of the reactions involved in the ring-opening polymerization (ROP) of lactide (LA) to give polylactides (PLAs) is presented along with competing reactions. Particular attention is given to the stereoselective polymerization of rac-LA to give heterotactic PLA and meso-LA to give syndiotactic PLA by aluminum Schiff-based catalysts and to the development of highly active group 2 metal single-site catalysts. Melt or solvent-free polymerization is also described along with reactions that lead exclusively to cyclic-polylactides.

Publisher

Walter de Gruyter GmbH

Subject

General Chemical Engineering,General Chemistry

Link

https://www.degruyter.com/downloadpdf/journals/pac/82/8/article-p1647.xml

Reference40 articles.

1. InStereoselective Polymerization with Single - Site Catalysts;Chisholm,2008

2. ic;Chisholm;Chem,2002

3. ic;Chisholm;Chem,2004

Cited by 84 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Phenoxy-imine supported hexacoordinate tetravalent titanium compounds: Synthesis, characterization and catalytic applications for ROP and ROCOP reactions;European Polymer Journal;2024-08

2. Unexpected Periodicity in Cationic Group 5 Initiators for the Ring-Opening Polymerization of Lactones;Inorganic Chemistry;2023-12-20

3. Coordination of ε-Caprolactone to a Cationic Niobium(V) Alkoxide Complex: Fundamental Insight into Ring-Opening Polymerization via Coordination–Insertion;Inorganic Chemistry;2023-09-11

4. Enzymes’ Power for Plastics Degradation;Chemical Reviews;2023-03-14

5. Ring-opening polymerization of cyclic esters mediated by zinc complexes coordinated with benzotriazo-based imino-phenoxy ligands;Polymer;2023-02