Cellulose recycling as a source of raw chirality-Reference-Cited by-同舟云学术

Cellulose recycling as a source of raw chirality

Published:2013-07-10 Issue:8 Volume:85 Page:1683-1692
ISSN:1365-3075
Container-title:Pure and Applied Chemistry
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Author:

Corne Valeria¹,Botta María Celeste¹,Giordano Enrique D. V.¹,Giri Germán F.¹,Llompart David F.¹,Biava Hernán D.¹,Sarotti Ariel M.¹,Mangione María I.¹,Mata Ernesto G.¹,Suárez Alejandra G.¹,Spanevello Rolando A.¹

Affiliation:

1. 1Instituto de Química Rosario, Facultad de Ciencias Bioquímicas y Farmacéuticas, Universidad Nacional de Rosario – CONICET, Suipacha 531, S2002LRK, Rosario, Argentina

Abstract

Modern organic chemistry requires easily obtainable chiral building blocks that show high chemical versatility for their application in the synthesis of enantiopure compounds. Biomass has been demonstrated to be a widely available raw material that represents the only abundant source of renewable organic carbon. Through the pyrolitic conversion of cellulose or cellulose-containing materials it is possible to produce levoglucosenone, a highly functionalized chiral structure. This compound has been innovatively used as a template for the synthesis of key intermediates of biologically active products and for the preparation of chiral auxiliaries, catalysts, and organocatalysts for their application in asymmetric synthesis.

Publisher

Walter de Gruyter GmbH

Subject

General Chemical Engineering,General Chemistry

Link

https://www.degruyter.com/downloadpdf/journals/pac/85/8/article-p1683.xml

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