Trace gas adsorption thermodynamics at the air−water interface: Implications in atmospheric chemistry

Author:

Valsaraj Kalliat T.1

Affiliation:

1. 1Cain Department of Chemical Engineering, Louisiana State University, Baton Rouge, LA 70803, USA

Abstract

The thermodynamics of adsorption of gaseous organic compounds such as polycyclic aromatic hydrocarbons (PAHs) on water films is reviewed and discussed. The various experimental methods available to determine the thermodynamic equilibrium constant and the structure–activity relationships to correlate and estimate the same are reviewed. The atmospheric implications of the adsorption and oxidation of PAHs at the air–water interface of thin films of water such as existing in fog droplets, ice films, and aerosols are also enumerated.

Publisher

Walter de Gruyter GmbH

Subject

General Chemical Engineering,General Chemistry

Reference60 articles.

1. In Air - Water Mass Transfer of Civil Engineers New York;Mackay;American Society,1991

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