Catalytic synthesis of amines and N-containing heterocycles: Amidate complexes for selective C–N and C–C bond-forming reactions

Author:

Eisenberger Patrick1,Schafer Laurel L.1

Affiliation:

1. 1Department of Chemistry, University of British Columbia, 6174 University Blvd., Vancouver, BC V6T 1Z1, Canada

Abstract

The direct, 100 % atom-economic, and selective synthesis of amines is a challenging task that can be achieved, making use of early transition-metal catalysts. Here we report the synthesis and application of group 4 and 5 high-oxidation-state metal amidate complexes in catalytic C–N (hydroamination) and C–C (hydroaminoalkylation) bond-forming reactions to access substituted amines.

Publisher

Walter de Gruyter GmbH

Subject

General Chemical Engineering,General Chemistry

Reference64 articles.

1. cr refs therein;Müller;Chem Rev,2008

2. ejoc;Müller;Doye Eur Org Chem,2008

3. ejic;Panda;Eur Inorg Chem,2008

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