Synthesis of transition-metal-containing poly(pyrazabole)s-Reference-Cited by-同舟云学术

Synthesis of transition-metal-containing poly(pyrazabole)s

Published:2006-01-01 Issue:7 Volume:78 Page:1407-1411
ISSN:1365-3075
Container-title:Pure and Applied Chemistry
language:
Short-container-title:

Author:

Matsumoto Fukashi¹,Chujo Yoshiki¹

Affiliation:

1. 1Department of Polymer Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510, Japan

Abstract

Novel organoboron polymers containing transition metals (Ni, Pd, Pt) and pyrazaboles in the main chain were prepared by Cu-catalyzed coupling polymerization. The Ni- and Pt-containing polymers showed MLCT (metal-to-ligand charge transfer) absorption, whereas the Pd-containing polymer did not demonstrate the absorption. Only the Pd-containing polymer exhibited the emission spectrum with a vibronic structure. These differences in the optical properties were studied in detail.

Publisher

Walter de Gruyter GmbH

Subject

General Chemical Engineering,General Chemistry

Link

https://www.degruyter.com/document/doi/10.1351/pac200678071407/pdf

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