Cycloruthenated compounds as efficient catalyst for asymmetric hydride transfer reaction-Reference-Cited by-同舟云学术

Cycloruthenated compounds as efficient catalyst for asymmetric hydride transfer reaction

Published:2006-01-01 Issue:2 Volume:78 Page:457-462
ISSN:1365-3075
Container-title:Pure and Applied Chemistry
language:
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Author:

Sortais Jean-Baptiste¹,Barloy Laurent¹,Sirlin Claude¹,de Vries André H. M.²,de Vries Johannes G.²,Pfeffer Michel¹

Affiliation:

1. 1CNRS, UMR 7177, Laboratoire de Synthèses Métallo-Induites, Université Louis Pasteur, 4, rue Blaise Pascal, 67000 Strasbourg, France

2. 2DSM Pharmaceutical Chemicals, Advanced Synthesis, Catalysis, and Development, P.O. Box 18, 6160 MD Geleen, The Netherlands

Abstract

Cycloruthenated complexes obtained by direct C-H activation of enantiopure aromatic primary and secondary amines are efficient catalysts in asymmetric hydride transfer reaction. Reduction of acetophenone has been achieved rapidly with enantiomeric excesses (ee's) ranging from 38 to 89 %. The importance of Ru-C bond in the catalytic efficiency is highlighted.

Publisher

Walter de Gruyter GmbH

Subject

General Chemical Engineering,General Chemistry

Link

https://www.degruyter.com/document/doi/10.1351/pac200678020457/pdf

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