Catalytic Studies of Complexes of Organic Compounds. Part-4: Synthesis, Characterization, Catalytic activity of Cd (II) Complex of Chiral Schiff base-Reference-Cited by-同舟云学术

Catalytic Studies of Complexes of Organic Compounds. Part-4: Synthesis, Characterization, Catalytic activity of Cd (II) Complex of Chiral Schiff base

Published:2021-02-28 Issue:1 Volume:37 Page:84-94
ISSN:2231-5039
Container-title:Oriental Journal Of Chemistry
language:en
Short-container-title:Orient. J. Chem

Author:

Patil C. J.¹^ORCID,Salve S. B.¹^ORCID

Affiliation:

1. Organic Research Laboratory, Smt. G. G. Khadse College, Muktainagar-425 306, MS, India.

Abstract

Chiral Schiff base ligand from 3,5-Diiodo-salicylaldehyde with a chiral amine (1S,2S)- (+)-1,2-Diaminocyclohexane is synthesized, and its Cd (II) complex was synthesized. These were analysed by the physical constant, TLC, colour, UV-Vis, FTIR and 1H NMR method. Also, efforts were made to study the catalytic activity of Cd (II) chiral schiff base complex. The oxidation of benzyl alcohol was used as model reaction using acetonitrile as solvent. The present reaction system was heterogeneous system of catalysis.

Publisher

Oriental Scientific Publishing Company

Subject

Drug Discovery,Environmental Chemistry,Biochemistry,General Chemistry

Reference45 articles.

1. 1. Schmidt, A. K. C.; Stark, C. B. W. TPAP-Catalysed direct oxidation of primary alcohol to carboxylic acid through stabilized aldehyde hydrates, Org. Lett., 2011, 13 (16) 4164-4167 htpps://doi.org/10.1021/ol2014335

2. 2. Biradar, A. V.; Dongare, M. K.; Umbarkar, S. B. Selective oxidation of aromatic primary alcohols to aldehydes using molybdenum acetylide oxo-peroxo complex as catalyst. Tetra. Lett., 2009, 50 (24) 2885-2888. htpps://doi.org/10.1016/j.tetlet.2009.03.178

3. 3. Zhao, M. M.; Li, J.; Mano, E.; Song, Z. J.; Tschaen, D. M. Oxidation of primary alcohol to carboxylic acids with sodium chlorite catalyzed by TEMPO and bleach: 4-Methoxy-phenyl acetic acid. Org. Synth., 2005, 81, 195-203. htpps://doi.org/10.15227/orgsyn.081.0195

4. 4. Mizugaki, H.; Ji, T.; Ebitani, K.; Kaneda, K. Highly efficient oxidation of alcohols to carbonyl compounds in the presence of molecular oxygen using a novel heterogeneous ruthenium catalyst. Tetra. Lett., 2002, 43 (40) 7179-7183. htpps://doi.org/10.1016/S0040-4039 (02)01678-7

5. 5. a) Madhava, A. S.; Patil, C. J.; Ramachandraiah, G.; Vyas, D. N. Electrochemical Studies of Schiff Base Complexes: Part-I. Electrochemical Studies of Ni (II) Schiff Base Complexes. Bull. Electrochem., 1995, 11 (9) 442, ISSN: 0256-1654, b) Madhava, A. S.; Patil, C. J.; Ramachandraiah, G.; Vyas, D. N. Electrochemical Studies of Schiff Base Complexes: Part-II. Electrochemical studies of some Cd (II) Schiff base complexes. Bull. Electrochem., 1996, 12, 355, ISSN:0256-1654

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