Adsorption of Acid Dye by Activated Carbon from Agricultural Solid Waste Leucona Leucocephala Seed Shell Waste: Kinetics, Equilibrium and Isotherm Study

Author:

Rajendran A Babu1,S Kalaiselvan2ORCID,R Padmavathi3

Affiliation:

1. Department of Chemistry, Government Higher Secondary School, Dharapuram, Tirupur, Tamilnadu, India.

2. Department of Chemistry, SNS College of Technology, Coimbatore, Tamilnadu, India

3. Department of Chemistry, M.Kumarasamy College of Engineering, Karur, Tamilnadu, India.

Abstract

Activated carbons from Leucaena leucocephala Seed Shell left over were generated accompanied by 10% phosphoric acid solution in the N2 atmosphere by chemical activation and their characteristics were investigated. SEM, FTIR and XRD analysis were used to analyse the characteristics of the triggered preparations. Isothermal models, namely the Freundlich and Langmuir representations, were the equilibrium studies carried out.. The equilibrium adsorption result was better suited to the isotherm model of Langmuir and its maximum monolayer adsorption potential for acid blue was 70.67 mg/g. Adsorption kinetics studies have shown that the best fit is provided by the pseudo second-order dynamic model. An intraparticle dispersion model demonstrated that the dissemination of the intraparticle was not a step of rate control. Studies of thermodynamics have shown that the sorption mechanism is spontaneous and exothermic in nature. The findings suggest that the seed shells of Leucaena leucocephala may be used as a possible adsorbent for Acid blue1 adsorption.

Publisher

Oriental Scientific Publishing Company

Subject

Pharmacology (medical),Complementary and alternative medicine,Pharmaceutical Science

Reference54 articles.

1. Y.T. Hung, H.H. Lo, L.K. Wang, J.R. Taricska, K.H. Li, Granular activated carbon adsorption, in: L.K. Wang, Y.T. Hung, N.K. Shammas (Eds.), Handbook of Environmental Engineering, vol. 3, Humana Press, Totowa, New Jersey, 2005, pp.573–634.

2. CrossRef

3. R. Taylor, Carbon blacks: production, properties and applications, in: H. Marsh, E.A. Heintz, F. Rodriguez-Reinoso (Eds.), Introduction to Carbon Technologies, Universidad de Alicante, Secretariado de Publicaciones, Alicante, 1997, pp. 167–210.

4. J. Lee, J. Kim, T. Hyeon, Recent progress in the synthesis of porous carbon materials, Adv. Mater. 18 (2006) 2073–2094.

5. CrossRef

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