Studies on Oxidation of Alcohols by Cerium (IV)-dimer in Aqueous Nitric acid-Reference-Cited by-同舟云学术

Studies on Oxidation of Alcohols by Cerium (IV)-dimer in Aqueous Nitric acid

Published:2022-02-28 Issue:1 Volume:38 Page:130-136
ISSN:2231-5039
Container-title:Oriental Journal Of Chemistry
language:en
Short-container-title:Orient. J. Chem

Author:

Bhuwan Chandra Bhuwan Chandra¹,Tamta Anshu¹,Rashmi Khulbe Rashmi Khulbe¹,Asha Kandpal Asha Kandpal¹,N.D. Kandpal N.D. Kandpal¹,Kailash Tamta Kailash Tamta²

Affiliation:

1. 1Physical Chemistry Laboratory, Department of Chemistry, Soban Singh Jeena University, Campus, Almora-263601, Uttarakhand, India.

2. 2Government Degree College Kanda, Bageshwar-263619, Uttarakhand, India.

Abstract

The oxidation of alcohols, n-propanol, 2-methoxy ethanol and 2-ethoxy ethanol by cerium (IV) in nitric acid leads to the formation of corresponding aldehydes. The reaction is first order with respect to Ce(IV). A Michaelis-Menten type kinetics is observed with respect to alcohols. The reaction is retarded by initial [Ce(IV)] with increase in concentration of oxidant. The reaction exhibits participation of 2 mole of cerium (IV) with 1 mole of alcohols. It has been concluded that Ce(IV)-dimer participate in the oxidation process and formation of free radical through complex ion formation in the nitric acid medium.

Publisher

Oriental Scientific Publishing Company

Subject

Drug Discovery,Environmental Chemistry,Biochemistry,General Chemistry

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