A Facile and Convenient Method to Reduce Organo Azides under Electrochemical Condition and Investigation of the Process thorough Cyclic Voltammetry
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Published:2022-10-31
Issue:5
Volume:38
Page:1236-1243
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ISSN:2231-5039
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Container-title:Oriental Journal Of Chemistry
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language:en
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Short-container-title:Orient. J. Chem
Author:
Lona Deena Paliakkara1ORCID, Selvaraj Savariraj Joseph1ORCID, Thomas K Joby2ORCID
Affiliation:
1. 1Department of Chemistry, St. Joseph’s College (Autonomous), Tiruchirappalli- 620 002, Tamil Nadu, India 2. 2Department of Chemistry, St. Thomas’ College (Autonomous), Thrissur- 680 001, Kerala, India.
Abstract
Organo azides are potential precursors for the preparation of amines by different ways of chemical reduction. In the present studies , a simple and more convenient method was developed to reduce to the corresponding amine or sulphonamide under electrochemical condition using sodium ascorbate as the promoter and platinum electrodes. The reduction was achieved with sulfonyl azides, alkyl and aryl azides with moderate to quantitative yields. Cyclic voltametry studies were carried out to study this electrochemical reduction.
Publisher
Oriental Scientific Publishing Company
Subject
Drug Discovery,Environmental Chemistry,Biochemistry,General Chemistry
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