Sequent Adsorption of phosphate ions by Copper ions Adsorbed on Tripolyphosphate Chitosan

Author:

Nguyen Thai Anh1ORCID,Bui Huu Trung2,Dang Vu Bich Hanh3ORCID,Trinh Thi Bich Huyen1ORCID,Le Thi Huynh Tram3,Nguyen Vinh Tien2ORCID

Affiliation:

1. 1Vietnam National University Ho Chi Minh City, Linh Trung Ward, Thu Duc City, Ho Chi Minh City, Vietnam.

2. 3Faculty of Chemical and Food Technology, Ho Chi Minh City University of Technology and Education, 01 Vo Van Ngan Street, Thu Duc City, Ho Chi Minh City, Vietnam.

3. 2Faculty of Environment and Natural Resources, Ho Chi Minh City University of Technology (HCMUT), 268 Ly Thuong Kiet St., Dist. 10, Ho Chi Minh City, Vietnam.

Abstract

In this study, we successfully crosslinked chitosan using STPP and produced chitosan beads to adsorb copper ions and subsequently phosphate ions from aqueous solutions. The optimal concentrations of chitosan (2% w/v) and STPP (7.5% w/v) during chitosan beads preparation and the optimal pH of 5.0 during adsorption were determined. Several adsorption models, including pseudo-first-order, pseudo-second-order, Langmuir, and Freundlich models, were used to evaluate the static adsorption experimental data. Moreover, the chitosan beads were applied in a dynamic adsorption column and several models including Bohart-Adam, Thomas, Yoon-Nelson, and Clark models were used to describe the system. This study showed that after adsorbing heavy metal ions, chitosan-STPP beads can be used for further adsorption of toxic anions from wastewater.

Publisher

Oriental Scientific Publishing Company

Subject

Drug Discovery,Environmental Chemistry,Biochemistry,General Chemistry

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