Reactions of MoCl5 and MoO2Cl2 with 4-Phenylimidazole-2-thiol and 2-Thiazoline-2-thiol-Reference-Cited by-同舟云学术

Reactions of MoCl5 and MoO2Cl2 with 4-Phenylimidazole-2-thiol and 2-Thiazoline-2-thiol

Published:2020-12-30 Issue:6 Volume:36 Page:1096-1102
ISSN:2231-5039
Container-title:Oriental Journal Of Chemistry
language:en
Short-container-title:Orient. J. Chem

Author:

Rani Deepika¹^ORCID

Affiliation:

1. 1Research Scholar registered with Punjab Technical University, Kapurthala-INDIA.

Abstract

Reactions of MoCl5/MoO2Cl2 with 4-phenylimidazole-2-thiol/2-thiazoline-2-thiol in CH3CN solvent in 1:1/1:2 molar ratios have been carried out at room temperature. Products obtained MoCl3(C9H7N2S)(CH3CN),[1]; MoCl2(C9H7N2S)(CH3CN), [2]; Mo2OCl4(C9H8N2S)2, [3] and Mo4O2Cl12(C9H7N2S)4, [4]; MoO2Cl3(C3H5NS2)2, [5] and Mo2O4Cl3(C3H5NS2)2, [6] have been analyzed and characterized by elemental analysis, FTIR, 1H NMR and LC-MS techniques. Compounds being moisture and air sensitive, these have been prepared in inert atmosphere using vacuum line and liquid nitrogen cooled traps. Fragments obtained in LC-MS spectra support the formulae derived.

Publisher

Oriental Scientific Publishing Company

Subject

Drug Discovery,Environmental Chemistry,Biochemistry,General Chemistry

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