The lightfastness of early synthetic organic dyes

Abstract

AbstractSynthetic organic colourants are extremely prominent in heritage collections, particularly throughout textiles. They are often generalized as highly light-sensitive; although, a broad distribution of lightfastness exists. This is evident in various fastness ratings published in late nineteenth century literature, the work of Schultz and Julius, and the Colour Index. In heritage conservation, much of the research related to light-sensitivity of dyed textiles has focused on natural colourants. This is likely due to a general interest in the dyes present on older objects, and the overwhelming selection of modern synthetic materials. To address this gap, a shortlist of targeted synthetic dyes was recently developed using census data for dye production and imports in the United States, and information gathered from the Colour Index. Our present work provides a follow up to the prior literature review, where a subset of samples from the published target list was used to evaluate lightfastness. To begin the study, a collection of dyed textiles from the last quarter of the nineteenth century was gathered from trade publications of the period, and those matching the target criteria were reserved for analysis. The lightfastness of more than 100 early synthetic dyes was then investigated using the historic materials. Test specimens were illuminated with a custom-built fadometer containing an LED light source that is characteristic of modern gallery lighting. Four batches of samples were exposed at 20 klx for approximately 6 months each, and diffuse reflectance was periodically measured with a portable spectrophotometer over white and black backgrounds. Measurements were taken at increasing light dose values to reach at least 85 Mlx·h per batch. Visible reflectance spectra were recorded in a dataset to document the colours as a function of light exposure, and foster future colorimetry research. Colour change was also calculated using the CIEDE2000 formula to assess lightfastness, and results were summarized as a resource to further develop risk analysis tools for exhibit lighting. In this paper, a detailed description of the test apparatus is presented with an overview of the lightfastness results and the resulting dataset. Comparisons are given with nineteenth century lightfastness data, and ISO values available in the Colour Index. It is hoped that the associated dataset will provide a foundation to be expanded over time with interest in further materials and test methods.