Gold determination in soil by ICP-MS: comparison of sample pretreatment methods

Abstract

AbstractAt present, the direct gold determination in geological samples by inductively coupled plasma mass spectrometry (ICP-MS) is still an arduous challenge due to both spectral and background interferences. It is very important and necessary to study the pretreatment processes; therefore, the polyurethane foam treatment and sample digestion methods are explored and compared here. The experimental results showed that the gold adsorption rate of treated foam was significantly improved as the impurities in the foam were cleaned up, and the potential difference of the liquid membrane was increased. Meanwhile, the combination of the foam enrichment and thiourea desorption achieved the selective adsorption and desorption of gold ions, eliminated the interference of coexisting ions, and perfected the detection limits. Compared with the traditional electric heating plate digestion method, microwave digestion, a closed digestion method, had the advantages of less sample and reagent dosage, short time consumption, high degree of automation, thorough digestion, good security, and environmental friendliness and met the requirements of green chemistry development. The proposed microwave digestion-foam enrichment-thiourea desorption-ICP-MS determination method was applied to the gold test in soil samples of the actual gold mining area. It has the great potential as a routine laboratory procedure.