Contrasting Chlorine Chemistry on Volcanic and Wildfire Aerosols in the Southern Mid‐Latitude Lower Stratosphere

Abstract

AbstractVolcanic eruptions and wildfires can impact stratospheric chemistry. We apply tracer‐tracer correlations to satellite data from Atmospheric Chemistry Experiment—Fourier Transform Spectrometer and the Halogen Occultation Experiment at 68 hPa to consistently compare the chemical impact on HCl after multiple wildfires and volcanic eruptions of different magnitudes. The 2020 Australian New Year (ANY) fire displayed an order of magnitude less stratospheric aerosol extinction than the 1991 Pinatubo eruption, but showed similar large changes in mid‐latitude lower stratosphere HCl. While the mid‐latitude aerosol loadings from the 2015 Calbuco and 2022 Hunga volcanic eruptions were similar to the ANY fire, little impact on HCl occurred. The 2009 Australian Black Saturday fire and 2021 smoke remaining from 2020 yield small HCl changes, at the edge of the detection method. These observed contrasts across events highlight greater reactivity for smoke versus volcanic aerosols at warm temperatures.