Influence of Aqueous‐Phase Chemistry on the Concentrations of PM2.5 and Hydrometers During the Development of Convective Clouds Over the Yellow Sea in July of 2017

Abstract

AbstractMeteorological processes are investigated during the development of deep convective clouds over the Yellow Sea inside a quasi‐stationary rainy front in the East Asian region. WRF‐Chem simulations were conducted to assess the effects of aqueous‐phase chemistry on the concentrations of PM2.5 and hydrometers in deep convective clouds and the associated precipitation. A reduction in the south‐north air temperature gradient induced an inactive quasi‐stationary rainy front with nonlinear zonal clouds during the Changma period in the East Asian region in 2017, causing intensified surface heating due to solar radiation. A mesoscale cyclone was formed near the Shantung Peninsula inside the inactive quasi‐stationary rainy front, extending the eastward tongue of the troughs across the Yellow Sea. Deep convective clouds (CC16 on July 16, CC17 on July 17, and CC18 on July 18) formed in a severe mode on the east side of the mesoscale cyclone over the Yellow Sea at midnight as the warm type, as the warm and humid south‐southwesterly winds present at that time produced convection energy. PM2.5 from eastern China flowed into warm‐type CC16, CC17, and CC18 areas, producing more cloud droplets below 500 hPa via activation. In contrast, the release of additional condensation heat amplifies updrafts within convective clouds during efficient nighttime environmental cooling, thereby enhancing the production of cold‐type ice, reaching altitudes of up to 15 km. The WRF‐Chem PM2.5 outcomes indicate a significant increase in heavy rainfall, exceeding 10 mm hr−1, particularly in the context of the development of cold‐type convective clouds.