Evidence of Sulfate‐Rich Fluid Alteration in Jezero Crater Floor, Mars

Author:

Siljeström Sandra1ORCID,Czaja Andrew D.2ORCID,Corpolongo Andrea2ORCID,Berger Eve L.3,Li An Y.4,Cardarelli Emily5ORCID,Abbey William5ORCID,Asher Sanford A.6,Beegle Luther W.5,Benison Kathleen C.7ORCID,Bhartia Rohit8ORCID,Bleefeld Benjamin L.9,Burton Aaron S.3ORCID,Bykov Sergei V.6ORCID,Clark Benton10ORCID,DeFlores Lauren5,Ehlmann Bethany L.11ORCID,Fornaro Teresa12ORCID,Fox Allie1314ORCID,Gómez Felipe15ORCID,Hand Kevin5ORCID,Haney Nikole C.13ORCID,Hickman‐Lewis Keyron1617,Hug William F.8,Imbeah Samara9,Jakubek Ryan S.13,Kah Linda C.18ORCID,Kivrak Lydia19,Lee Carina1314,Liu Yang5ORCID,Martínez‐Frías Jesús20ORCID,McCubbin Francis M.3ORCID,Minitti Michelle21ORCID,Moore Kelsey5,Morris Richard V.3ORCID,Núñez Jorge I.22ORCID,Osterhout Jeffrey T.5,Phua Yu Yu11ORCID,Randazzo Nicolas23,Hollis Joseph Razzell16,Rodriguez Carolina9ORCID,Roppel Ryan6ORCID,Scheller Eva L.24,Sephton Mark25ORCID,Sharma Shiv K.26ORCID,Sharma Sunanda5,Steadman Kim5ORCID,Steele Andrew27,Tice Michael28,Uckert Kyle5ORCID,VanBommel Scott29,Williams Amy J.19ORCID,Williford Kenneth H.30,Winchell Katherine931,Wu Megan Kennedy9,Yanchilina Anastasia32ORCID,Zorzano Maria‐Paz15ORCID

Affiliation:

1. RISE Research Institutes of Sweden Stockholm Sweden

2. Department of Geosciences University of Cincinnati Cincinnati OH USA

3. NASA Johnson Space Center Houston TX USA

4. Department of Earth and Space Sciences/Astrobiology Program University of Washington Seattle WA USA

5. Jet Propulsion Laboratory California Institute of Technology Pasadena CA USA

6. Department of Chemistry University of Pittsburgh Pittsburgh PA USA

7. Department of Geology and Geography West Virginia University Morgantown WV USA

8. Photon Systems Inc. Covina CA USA

9. Malin Space Science Systems San Diego CA USA

10. Space Science Institute Boulder CO USA

11. Division of Geological and Planetary Sciences California Institute of Technology Pasadena CA USA

12. INAF‐Astrophysical Observatory of Arcetri Florence Italy

13. Jacobs JETS NASA Johnson Space Center Houston TX USA

14. LPI Houston TX USA

15. Centro de Astrobiología (CAB) CSIC‐INTA Madrid Spain

16. The Natural History Museum London UK

17. Dipartimento di Scienze Biologiche Geologiche e Ambientali Università di Bologna Bologna Italy

18. Department of Earth and Planetary Sciences University of Tennessee Knoxville TN USA

19. Department of Geological Sciences University of Florida Gainesville FL USA

20. Institute of Geosciences IGEO (CSIC‐UCM) Madrid Spain

21. Framework Silver Spring MD USA

22. Johns Hopkins University Applied Physics Laboratory Laurel MD USA

23. Department of Earth and Atmospheric Sciences University of Alberta Edmonton AB Canada

24. Department of Earth, Atmospheric, and Planetary Sciences MIT Cambridge MA USA

25. Imperial College London London UK

26. Hawaii Institute of Geophysics & Planetology University of Hawaii Honolulu HI USA

27. Carnegie Institution of Washington Washington DC USA

28. Texas A&M University College Station TX USA

29. Department of Earth and Planetary Sciences Washington University in St. Louis St. Louis MO USA

30. Blue Marble Space Institute of Science Seattle WA USA

31. Arizona State Univeristy Tempe AZ USA

32. Impossible Sensing, LLC St. Louis MO USA

Abstract

AbstractSulfur plays a major role in martian geochemistry and sulfate minerals are important repositories of water. However, their hydration states on Mars are poorly constrained. Therefore, understanding the hydration and distribution of sulfate minerals on Mars is important for understanding its geologic, hydrologic, and atmospheric evolution as well as its habitability potential. NASA's Perseverance rover is currently exploring the Noachian‐age Jezero crater, which hosts a fan‐delta system associated with a paleolake. The crater floor includes two igneous units (the Séítah and Máaz formations), both of which contain evidence of later alteration by fluids including sulfate minerals. Results from the rover instruments Scanning Habitable Environments with Raman and Luminescence for Organics and Chemistry and Planetary Instrument for X‐ray Lithochemistry reveal the presence of a mix of crystalline and amorphous hydrated Mg‐sulfate minerals (both MgSO4·[3–5]H2O and possible MgSO4·H2O), and anhydrous Ca‐sulfate minerals. The sulfate phases within each outcrop may have formed from single or multiple episodes of water activity, although several depositional events seem likely for the different units in the crater floor. Textural and chemical evidence suggest that the sulfate minerals most likely precipitated from a low temperature sulfate‐rich fluid of moderate pH. The identification of approximately four waters puts a lower constraint on the hydration state of sulfate minerals in the shallow subsurface, which has implications for the martian hydrological budget. These sulfate minerals are key samples for future Mars sample return.

Funder

NASA Headquarters

National Science Foundation

Jet Propulsion Laboratory

Agenzia Spaziale Italiana

Johnson Space Center

UK Space Agency

Ministerio de Ciencia e Innovación

Publisher

American Geophysical Union (AGU)

Subject

Space and Planetary Science,Earth and Planetary Sciences (miscellaneous),Geochemistry and Petrology,Geophysics

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