Affiliation:
1. Institute of Geological Sciences University of Bern Bern Switzerland
2. Now at Paul Scherrer Institute Villigen PSI Switzerland
3. Department of Chemistry, Biochemistry and Pharmaceutical Sciences University of Bern Bern Switzerland
4. Now at Shriram Center for Bioengineering and Chemical Engineering Stanford University Stanford CA USA
Abstract
AbstractMagnetic pore fabrics (MPFs) are a promising approach to explore the 3D pore space of rocks. There exist empirical relationships between the orientation, degree, and shape of MPF with pore space geometry and permeability anisotropy. Nevertheless, the precise nature of these relationships remains elusive. A common assumption in MPF studies is that ferrofluid uniformly fills the pore space, establishing a constant nanoparticle density and magnetic properties in space and time. However, this assumption is challenged by observations of particle sedimentation and time‐dependent magnetic properties, which render the quantitative interpretation of MPFs challenging. This study explores the physical and chemical stability of ferrofluid, mobility of particles after impregnation, and the magnetic properties of impregnated rocks over time. Water‐based ferrofluids are physically more stable than oil‐based ferrofluids, though with higher magnetic variability. In impregnated rock, magnetic nanoparticles display a certain degree of mobility, resulting in changes in MPF degree and shape. When ferrofluid is mixed with epoxy, particles are less mobile, though some changes were observed both during polymerization and aging. The susceptibility of ferrofluid‐epoxy mixtures is lower than for ferrofluid and carrier liquid at the same concentration. Interestingly, the susceptibility of impregnated rock increases over time, regardless of the ferrofluid used for the impregnation. Understanding and controlling these processes will enhance the reliability of MPF interpretations and increase the applicability of the method.
Funder
Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung
Publisher
American Geophysical Union (AGU)
Subject
Geochemistry and Petrology,Geophysics