Equilibrium Fractionation of Stable Strontium Isotopes During Adsorption to Mn Oxides

Abstract

AbstractUnderstanding the stable strontium isotope fractionation between seawater and ferromanganese crusts/nodules is crucial for reconstructing seawater Sr isotopic history. This study explores stable Sr isotope fractionation during adsorption to manganese oxides, as preliminary experiments indicated their higher Sr adsorption capacity compared to iron oxides. We observed that equilibrium in concentration and isotopic composition can be achieved within a day. The lighter isotope (86Sr) is preferentially adsorbed, with the fractionation extent showing no significant change with respect to reaction time, pH, or Sr concentration under low ionic strength conditions (−0.14‰). Equilibrium fractionation processes, rather than Rayleigh fractionation, more accurately represent the isotopic composition trends of dissolved and adsorbed Sr. Experiments in synthetic seawater demonstrated greater Sr isotope fractionation (−0.20‰) compared to low ionic‐strength solutions. This fractionation during adsorption by manganese oxides in synthetic seawater is consistent with the isotopic discrepancy between seawater and ferromanganese nodules, suggesting that Mn oxide adsorption is the primary mechanism for Sr accumulation in ferromanganese deposits. These results imply that ferromanganese deposit Sr isotopic compositions could be proxies for reconstructing seawater Sr isotopic history, which is influenced by carbonate burial and continental weathering, reflecting the global carbon cycle changes.