Predicting Carbonate Chemistry on the Northwest Atlantic Shelf Using Neural Networks

Author:

Lima Ivan D.1ORCID,Wang Zhaohui A.1ORCID,Cameron Louise P.1,Grabowski Jonathan H.2,Rheuban Jennie E.1ORCID

Affiliation:

1. Department of Marine Chemistry and Geochemistry Woods Hole Oceanographic Institution Woods Hole MA USA

2. Marine Science Center Northeastern University Nahant MA USA

Abstract

AbstractThe Northwest Atlantic Shelf (NAS) region has experienced accelerated warming, heatwaves, and is susceptible to ocean acidification, yet also suffers from a paucity of carbonate chemistry observations, particularly at depth. We address this critical data gap by developing three different neural network models to predict dissolved inorganic carbon (DIC) and total alkalinity (TA) in the NAS region from more readily available hydrographic and satellite data. The models predicted DIC withr2between 0.913–0.963 and root mean square errors (RMSE) between 15.4–23.7 (μmol kg−1) and TA withr2between 0.986–0.983 and RMSE between 9.0–10.4 (μmol kg−1) on an unseen test data set that was not used in training the models. Cross‐validation analysis revealed that all models were insensitive to the choice of training data and had good generalization performance on unseen data. Uncertainty in DIC and TA were low (coefficients of variation 0.1%–1%). Compared with other predictive models of carbonate system variables in this region, a larger and more diverse data set with full seasonal coverage and a more sophisticated model architecture resulted in a robust predictive model with higher accuracy and precision across all seasons. We used one of the models to generate a reconstructed seasonal distribution of carbonate chemistry fields based on DIC and TA predictions that shows a clear seasonal progression and large spatial gradients consistent with observations. The distinct models will allow for a range of applications based on the predictor variables available and will be useful to understand and address ocean sustainability challenges.

Funder

National Oceanic and Atmospheric Administration

Publisher

American Geophysical Union (AGU)

Subject

Paleontology,Atmospheric Science,Soil Science,Water Science and Technology,Ecology,Aquatic Science,Forestry

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