Spatial and Temporal Redox Heterogeneity Controlled by a Fe(II), Anoxic Upwelling System in the Early Mesoproterozoic Ocean

Abstract

AbstractThe availability of oxygen and nutrients during the Mesoproterozoic (1.6–1.0 Ga) is thought to influence the rate of eukaryote evolution. The cause of the transition from low productivity in the upper Wumishan Formation to organic‐rich sediments in the Hongshuizhuang Formation remains unknown. We report FeHR/FeT, Fepy/FeHR, MoEF, UEF, VEF, and [Ce/Ce*]SN in one core of the Yanliao Basin to study the redox evolution and compare it with other sections in different depths of the Yanliao Basin to get clues of the spatial and temporal redox heterogeneity. Mo‐U covariation, low Co × Mn and CoEF × MnEF, and distribution patterns of trace metals indicate the upwelling events. An upwelling system could fuel nutrients to promote productivity levels in surface water and contribute to anoxic deep waters. The uniformly positive δ15N values are interpreted as sufficient NO3− reduction via denitrification and dissimilatory nitrate reduction to ammonium in a ferruginous upwelling condition.