Airborne Observations Constrain Heterogeneous Nitrogen and Halogen Chemistry on Tropospheric and Stratospheric Biomass Burning Aerosol-Reference-Cited by-同舟云学术

Airborne Observations Constrain Heterogeneous Nitrogen and Halogen Chemistry on Tropospheric and Stratospheric Biomass Burning Aerosol

Published:2024-02-12 Issue:4 Volume:51 Page:
ISSN:0094-8276
Container-title:Geophysical Research Letters
language:en
Short-container-title:Geophysical Research Letters

Author:

Decker Zachary C. J.¹²³⁴^ORCID,Novak Gordon A.¹²,Aikin Kenneth¹²^ORCID,Veres Patrick R.¹⁵,Neuman J. Andrew¹²,Bourgeois Ilann¹²⁶,Bui T. Paul⁷^ORCID,Campuzano‐Jost Pedro²³^ORCID,Coggon Matthew M.¹²^ORCID,Day Douglas A.²³^ORCID,DiGangi Joshua P.⁸^ORCID,Diskin Glenn S.⁸^ORCID,Dollner Maximilian⁹^ORCID,Franchin Alessandro¹²¹⁰,Fredrickson Carley D.¹¹^ORCID,Froyd Karl D.¹²^ORCID,Gkatzelis Georgios I.¹²¹²^ORCID,Guo Hongyu²³,Hall Samuel R.¹⁰^ORCID,Halliday Hannah⁸^ORCID,Hayden Katherine¹³,Holmes Christopher D.¹⁴^ORCID,Jimenez Jose L.²³^ORCID,Kupc Agnieszka¹²⁹,Lindaas Jakob¹⁵^ORCID,Middlebrook Ann M.¹,Moore Richard H.⁸^ORCID,Nault Benjamin A.¹⁶^ORCID,Nowak John B.⁸^ORCID,Pagonis Demetrios²³¹⁷,Palm Brett B.⁵¹¹^ORCID,Peischl Jeff¹²^ORCID,Piel Felix M.¹⁸¹⁹,Rickly Pamela S.¹²²⁰,Robinson Michael A.¹²³^ORCID,Rollins Andrew W.¹^ORCID,Ryerson Thomas B.¹^ORCID,Schill Gregory P.¹^ORCID,Sekimoto Kanako²¹,Thompson Chelsea R.¹^ORCID,Thornhill Kenneth L.⁸²²^ORCID,Thornton Joel A.¹¹^ORCID,Ullmann Kirk¹⁰^ORCID,Warneke Carsten¹^ORCID,Washenfelder Rebecca A.¹²³,Weinzierl Bernadett⁹^ORCID,Wiggins Elizabeth B.⁸^ORCID,Williamson Christina J.¹²²⁴²⁵,Winstead Edward L.⁸²²^ORCID,Wisthaler Armin¹⁸¹⁹^ORCID,Womack Caroline C.¹²,Brown Steven S.¹³^ORCID

Affiliation:

1. NOAA Chemical Sciences Laboratory (CSL) Boulder CO USA

2. Cooperative Institute for Research in Environmental Sciences University of Colorado Boulder Boulder CO USA

3. Department of Chemistry University of Colorado Boulder Boulder CO USA

4. Now at Laboratory of Atmospheric Chemistry Paul Scherrer Institute (PSI) Villigen Switzerland

5. Now at National Center for Atmospheric Research Boulder CO USA

6. Now at Université Savoie Mont Blanc INRAE CARRTEL Thonon‐les‐Bains France

7. NASA Ames Research Center Moffett Field CA USA

8. NASA Langley Research Center Hampton VA USA

9. Faculty of Physics Aerosol Physics and Environmental Physics University of Vienna Vienna Austria

10. Atmospheric Chemistry Observations and Modeling Laboratory National Center for Atmospheric Research Boulder CO USA

11. Department of Atmospheric Sciences University of Washington Seattle WA USA

12. Now at Institute of Energy and Climate Research IEK‐8: Troposphere Forschungszentrum Jülich GmbH Jülich Germany

13. Air Quality Research Division (AQRD) Environment and Climate Change Canada Toronto ON Canada

14. Department of Earth, Ocean, and Atmospheric Science Florida State University Tallahassee FL USA

15. Department of Atmospheric Science Colorado State University Fort Collins CO USA

16. Center for Aerosol and Cloud Chemistry Aerodyne Research, Inc. Billerica MA USA

17. Now at Department of Chemistry and Biochemistry Weber State University Ogden UT USA

18. Institute for Ion Physics and Applied Physics University of Innsbruck Innsbruck Austria

19. Department of Chemistry University of Oslo Oslo Norway

20. Now at Colorado Department of Public Health and Environment Denver CO USA

21. Graduate School of Nanobioscience Yokohama City University Yokohama Japan

22. Science Systems and Applications, Inc. (SSAI) Hampton VA USA

23. Now at Cooperative Institute for Research in Environmental Sciences University of Colorado Boulder Boulder CO USA

24. Now at Finnish Meteorological Institute Helsinki Finland

25. Now at Institute for Atmospheric and Earth System Research/Physics Faculty of Science University of Helsinki Helsinki Finland

Abstract

AbstractHeterogeneous chemical cycles of pyrogenic nitrogen and halides influence tropospheric ozone and affect the stratosphere during extreme Pyrocumulonimbus (PyroCB) events. We report field‐derived N2O5 uptake coefficients, γ(N2O5), and ClNO2 yields, φ(ClNO2), from two aircraft campaigns observing fresh smoke in the lower and mid troposphere and processed/aged smoke in the upper troposphere and lower stratosphere (UTLS). Derived φ(ClNO2) varied across the full 0–1 range but was typically <0.5 and smallest in a PyroCB (<0.05). Derived γ(N2O5) was low in agricultural smoke (0.2–3.6 × 10−3), extremely low in mid‐tropospheric wildfire smoke (0.1 × 10−3), but larger in PyroCB processed smoke (0.7–5.0 × 10−3). Aged biomass burning aerosol in the UTLS had a higher γ(N2O5) of 17 × 10−3 that increased with sulfate and liquid water, but that was 1–2 orders of magnitude lower than values for aqueous sulfuric aerosol used in stratospheric models.

Publisher

American Geophysical Union (AGU)

Link

https://agupubs.onlinelibrary.wiley.com/doi/pdf/10.1029/2023GL107273

Reference41 articles.

1. Production of N2O5 and ClNO2 through Nocturnal Processing of Biomass-Burning Aerosol

2. Wildfire smoke destroys stratospheric ozone

3. Large contribution of biomass burning emissions to ozone throughout the global remote troposphere

Cited by 1 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Emissions and Atmospheric Chemistry of Furanoids from Biomass Burning: Insights from Laboratory to Atmospheric Observations;ACS Earth and Space Chemistry;2024-04-08