Effect of AOT/Heptane Reverse Micelles on Oxidation of Ferroin by Metaperiodate: Kinetic and Mechanistic Aspects-Reference-Cited by-同舟云学术

Effect of AOT/Heptane Reverse Micelles on Oxidation of Ferroin by Metaperiodate: Kinetic and Mechanistic Aspects

Published:2023-11-11 Issue:4 Volume:10 Page:1099-1106
ISSN:2149-0120
Container-title:Journal of the Turkish Chemical Society Section A: Chemistry
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Author:

BODASİNGİ Leela Kumari¹^ORCID,PULİPAKA Shyamala²^ORCID,KİLANA Venkata Nagalakshmi³^ORCID

Affiliation:

1. Chaitanya Women’s Degree & P.G College, Gajuwaka, Visakhapatnam

2. ANDHRA UNIVERSITY

3. Gayatri Vidya Parishad college of Engineering (Autonomous)

Abstract

A kinetic study of the oxidation of Ferroin, [Fe(phen)3]2+ by metaperiodate (IO4-) has been carried out in AOT/heptane reverse micelles by changing W = ([H2O]/[AOT]) and AOT concentration. The reaction order is first order with respect to Ferroin, while zero order with respect to IO4-. The reaction rate is faster in aqueous medium compared to AOT reverse micelles by eight times. The oxidation rate increases with an increase in the value of W (at fixed surfactant concentration, [AOT]) and decreases with AOT concentration. The effect of W on rate is elucidated based on the low dielectric constant of the water pool. Berezin's pseudo-phase model has been applied to explain the effect of AOT on rate.

Publisher

The Turkish Chemical Society

Subject

General Chemistry

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