Flow-injection analysis with a small cylindrical wire type electrode-Reference-Cited by-同舟云学术

Flow-injection analysis with a small cylindrical wire type electrode

Published:2004-09-01 Issue:3 Volume:2 Page:480-490
ISSN:2391-5420
Container-title:Open Chemistry
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Author:

Denchev Zhivko¹,Nikolov Nikola¹

Affiliation:

1. 1Department of Analytical Chemistry, University of Plovdiv, 24, Tsar Assen St., 4000, Plovdiv, Bulgaria

Abstract

AbstractAn amperometric detector with a small thin mercury film electrode is described. The device demonstrates advantageous operational characteristics such as small dispersion (D<2) and “memory effect” (me<0.6%), extensive maximum sample frequency (msf −200 samples/h), and high sensitivity. It has been proven useful in flow-injection analysis at a constant potential under hydrodynamic conditions.

Publisher

Walter de Gruyter GmbH

Subject

Materials Chemistry,General Chemistry

Link

http://link.springer.com/content/pdf/10.2478/BF02476202.pdf

Reference15 articles.

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2. Zh.I. Denchev, N.K. Nikolov and L. Ilcheva: “Analytical applications of graphite electrode with Bis(diisopropyloxithiophosphon) Disulfide”, Talanta, Vol. 44, (1997), pp. 749–753.

3. V.G. Levich: Physico-Chemical Hydrodynamics, (in Russian), Phismathgiz, Moscow, 1959.

4. J. Wang: “Theoretical Treatment of Intermediate Electrolysis Electrochemical Detectors”, Analytica Chimica Acta, Vol. 127, (1981), pp. 157–164.

5. J.M. Elbicki, D.M. Morgan and S.G. Weber: “Theoretical and Practical Limitations on the Optimisation of Amperometric Detectors”, Analytical Chemistry, Vol. 56, (1984), pp. 978–985.

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