Oxidation of cyclic ketones to dicarboxylic acids-Reference-Cited by-同舟云学术

Oxidation of cyclic ketones to dicarboxylic acids

Published:2018-12-01 Issue:4 Volume:20 Page:102-107
ISSN:1899-4741
Container-title:Polish Journal of Chemical Technology
language:en
Short-container-title:

Author:

Lisicki Dawid¹,Orlińska Beata¹

Affiliation:

1. Silesian University of Technology, Faculty of Chemistry, Department of Chemical Organic Technology and Petrochemistry, Krzywoustego 4, 44-100 Gliwice , Poland

Abstract

Abstract This paper reports the results of studies concerning an alternative method of obtaining dicarboxylic acids, which consist of the oxidation of cyclic ketones with oxygen or air. The raw materials used were cyclopentanone, cycloheptanone, cyclooctanone, cyclododecanone, 1-tetralon, 2-methylhexanone, 3-methylcyclohexanone and 4-methylcyclohexanone. Oxidation reactions were conducted at 70-100°C, under pressure of 0.1 or 0.4 MPa, for 6 h, utilizing the salts of transition metals as catalyst and acetic acid as solvent. For example, when cyclopentanone was oxidized in the presence of Mn(II) salt, a conversion above 98% and selectivity to glutaric acid up to 68% were obtained. Among synthesized dicarboxylic acids, 1,12-dodecanoic acid was obtained with the highest selectivity of 76%.

Publisher

Walter de Gruyter GmbH

Subject

General Chemical Engineering,General Chemistry,Biotechnology

Link

https://www.sciendo.com/pdf/10.2478/pjct-2018-0061

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